8462/1H June 2021

8  ​​​​ This question is about the reaction between hydrogen sulfide (H2S) and oxygen.

The​​ equation​​ for​​ the​​ reaction​​ is:

2​​ H2S(g)​​ +​​ 3​​ O2(g)​​ ​​ 2​​ H2O(g)​​ +​​ 2​​ SO2(g)

8-1  ​​​​ What​​ does​​ H2O (g)​​ represent?      ​​ ​​ ​​ ​​ ​​ ​​​​ [1 mark]

ANSWER

Water vapour / Steam

8-2  ​​​​ Calculate​​ the​​ volume​​ of​​ oxygen​​ required​​ to​​ react​​ with​​ 50​​ cm3​​ of​​ hydrogen​​ sulfide.  ​​ ​​ ​​ ​​ ​​ ​​​​ [1​​ mark]

ANSWER

75 cm3​​ 

 

8-3  ​​​​ Figure 6 shows part of the reaction profile for the reaction.​​ The reaction is exothermic.

Complete Figure 6.

You should:

  • complete​​ the​​ profile​​ line

  • label​​ the​​ activation​​ energy

  • label​​ the​​ overall​​ energy​​ change.

 

  ​​ ​​ ​​ ​​​​ [3​​ marks]

ANSWER

 

 

8-4  ​​​​ Figure​​ 7​​ shows​​ the​​ displayed​​ formula​​ equation​​ for​​ the​​ reaction​​ of​​ hydrogen​​ sulfide with oxygen.

 

Figure​​ 7

 

Table​​ 5​​ shows​​ some​​ of​​ the​​ bond​​ energies.

Table​​ 5

In the reaction the energy released forming new bonds is 1034 kJ/mol greater than the energy needed to break existing bonds.

 

Calculate​​ the​​ bond​​ energy​​ X​​ for​​ the​​ ​​ bond. Use​​ Figure 7​​ and​​ Table 5. ​​ ​​ ​​ ​​​​ [5​​ marks]

ANSWER

Energy required to break bonds ofreactant=2H-S+3O=O

=2364+3498

=2950KJmol

Enery required for new bonds forming=2H-O-H+2(O=S=O)

=22×464+22X

=1856+4X

total enery in bond formed=2950+1034

=3984kJ

Now​​ 

3984=4×464+4X

X=532kJ