8462/1H June 2021

1  ​​ ​​​​ This question is about carbon and its compounds.

Fullerenes are molecules of carbon atoms.

The​​ first​​ fullerene​​ to​​ be​​ discovered​​ was​​ Buckminsterfullerene​​ (C60).

1-1  ​​ ​​​​ What​​ shape​​ is​​ a​​ Buckminsterfullerene​​ molecule? ​​ [1​​ mark]

ANSWER

Spherical

1-2  ​​ ​​​​ Give​​ one​​ use​​ of​​ a​​ fullerene.  ​​ ​​ ​​​​ [1 mark]

ANSWER

  • For delivery of drugs throughout or specific parts of the body and/or cells – the drugs are often carried inside the hollow​​ center of the fullerene molecule;

  • In lubricants to reduce friction when metal parts of machines move past each other – the spherical shape of the molecule helps and allows molecules to roll past each other hence reducing friction;

  • As catalysts – a lot of​​ research is taking place into the use of fullerenes as catalysts and a wide range of potential​​ applications are being found.

 

 

1-3  ​​​​ Propanone is a compound of carbon, hydrogen and oxygen. Figure 1 shows the dot and cross diagram for a propanone molecule.​​ 

 

 

 

 

Figure 1

 

Complete​​ Figure​​ 2​​ to​​ show​​ a​​ propanone​​ molecule. Use a line to represent each single bond.​​        ​​ ​​ ​​​​ [1 mark]

Use​​ Figure​​ 1.

Figure​​ 2

ANSWER

 

 

 

1-4  ​​​​ Determine​​ the​​ molecular​​ formula​​ of​​ propanone.

 

Use​​ Figure​​ 1.         ​​ ​​ ​​​​ [1​​ mark]

 

ANSWER

 

C3H6O

 

1-5  ​​ ​​​​ Propanone​​ is​​ a​​ liquid​​ with​​ a​​ low​​ boiling​​ point.

 

Why​​ does​​ propanone​​ have​​ a​​ low​​ boiling​​ point?  ​​ ​​ ​​​​ [1​​ mark]

 

ANSWER

The​​ intermolecular​​ forces​​ are​​ weak

 

1-6  ​​ ​​​​ Figure​​ 3​​ represents​​ the​​ structure​​ of​​ graphite

Figure​​ 3

 

​​ Explain​​ why​​ graphite​​ is:

  • a​​ good​​ electrical​​ conductor

  • soft​​ and​​ slippery.[6​​ marks]

 

You should answer in terms of structure and bonding.

ANSWER

  • Graphite is a giant covalent bond structure and​​ contains delocalized electrons (free electrons). These electrons​​ can move throughout the structure of graphite, carrying charge from place to place and allowing graphite to be a good conductor of electricity;

  • Graphite is made up of layers of carbon​​ atoms. Because these layers are weakly bonded together, they slide over​​ each other easily. This is what makes graphite a soft and slippery​​ material.​​